- CAS
- Purity
- 1719-58-0
- 99%
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Chloro(dimethyl)vinylsilane (Dimethylvinylchlorosilane, Vinyldimethylchlorosilosilane, C4H9ClSi) is an organosilicon compound that is a clear light beige to amber liquid. It is known for its participation in the preparation of 1,1,2,2-tetramethyl-1,2-divinyldisilane and undergoes [2+4] cycloaddition reaction with t-butyllithium in the presence of 2,3-dimethyl-1,3-butadiene to afford cycloadducts. It has a boiling point of 82-83°C and a density of 0.874 gmL^-1 at 25°C.
Metallacycloalkanones have been prepared by the cyclic hydroboration of dialkenyl silanes. In order to obtain one such dialkenyl silane, chlorodimethylvinylsilanewas allylated with allyl magnesium bromide (eq 4).The dialkenyl silane was then hydroborated sequentially with thexylborane, followed by treatment with potassium cyanide, trifluoroacetic anhydride, and finally hydrogen peroxide in sodium hydroxide to produce the silacycloheptanone (eq 4).Cyclic silylketones were then further reacted to form acyclic compounds with chiral centers that are difficult to introduce without the use of the silicon tether.
The CAS number of CHLORODIMETHYLVINYLSILANE is 1719-58-0.
More information of CHLORODIMETHYLVINYLSILANE 1719-58-0 are:
|
CAS?Number |
1719-58-0 |
|
Density |
0.874 |
|
Boiling Point |
82-83 °C(lit.) |
|
Flash Point |
-4 ºC |
|
Vapor Pressure |
95hPa at 20℃ |
|
Refractive Index |
n20/D 1.414(lit.) |
|
HS CODE |
29319090 |
|
PSA |
0.00000 |
|
LogP |
2.15550 |
The chemical formula of?CHLORODIMETHYLVINYLSILANE is C4H9ClSi which containing 4 Carbon atoms,9 Hydrogen atoms,1 Chlorine atoms and 1 Silicon atoms,and the molecular weight, and the molecular weight of CHLORODIMETHYLVINYLSILANE is 120.654
Chloro(dimethyl)vinylsilane (Dimethylvinylchlorosilane, Vinyldimethylchlorosilosilane, C4H9ClSi) is an organosilicon compound that is a clear light beige to amber liquid. It is known for its participation in the preparation of 1,1,2,2-tetramethyl-1,2-divinyldisilane and undergoes [2+4] cycloaddition reaction with t-butyllithium in the presence of 2,3-dimethyl-1,3-butadiene to afford cycloadducts. It has a boiling point of 82-83°C and a density of 0.874 gmL^-1 at 25°C.
InChI:InChI=1/C4H8ClSi/c1-6(2)4-3-5/h3-4H,1-2H3/b4-3+
Relevant articles related to CHLORODIMETHYLVINYLSILANE:
|
Article |
Source |
|
- |
Vdovin,V.M. et al. , (1961) |
|
Synthesis method for dimethylvinylchlorosilane |
- Paragraph 0028-0038, (2019/02/19) |
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