- CAS
- Purity
- 2926-30-9
- 99%
Location:Home > Pharmaceutical
|
General Description |
Sodium trifluoromethanesulfonate (Sodium triflate or NaOTf) is an efficient catalyst as well as a reagent in many organic reactions. The prominent application includes catalytic asymmetric Mannich-type reactions, Mannich-type reactions in water, and Diels-Alder reactions. |
InChI:InChI=1/CHF3O3S.Na/c2-1(3,4)8(5,6)7;/h(H,5,6,7);/q;+1/p-1
The invention relates to a preparation m...
The first catalytic asymmetric carboannu...
Rhenium(I) compounds [Re(CO)3(Hdmpz)2(am...
The invention concerns a method for prep...
Trifluoro-methanesulfonate((Z)-1-butyl-2-trifluoromethanesulfonyloxy-hex-1-enyl)-triphenyl-phosphonium;
5-decyne
sodium triflate
triphenylphosphine
| Conditions | Yield |
|---|---|
|
With
sodium amalgam;
In
tetrahydrofuran;
at 5 ℃;
for 17h;
|
45%
|
ethanol
Trifluoromethanesulfonyl fluoride
trifluoromethanesulfonic acid ethyl ester
sodium triflate
| Conditions | Yield |
|---|---|
|
100°C, 1 h, absolute ethanol;
|
0%
|
|
100°C, 1 h, absolute ethanol;
|
0%
|
Langlois reagent
barium trifluoromethanesulfonate
Trifluoro-methanesulfonate((Z)-1-methyl-2-phenyl-2-trifluoromethanesulfonyloxy-vinyl)-triphenyl-phosphonium;
Trifluoro-methanesulfonate((Z)-1-butyl-2-trifluoromethanesulfonyloxy-hex-1-enyl)-triphenyl-phosphonium;
N-fluoropyridinium triflate
1-fluoro-2,4,6-trimethylpyridinium trifluoromethanesulfonate
N-Fluoro-2-fluoromethyl-4,6-dimethylpyridinium triflate
N-Fluoro-4-phenylpyridinium triflate