- CAS
- Purity
- 14917-83-0
- 99%
Bicyclo[4.1.0]hept-2-ene-3-carboxaldehyde, 7,7-dimethyl-, (1R,6S)-
Quality Factory Sells Top Purity 99% Bicyclo[4.1.0]hept-2-ene-3-carboxaldehyde, 7,7-dimethyl-, (1R,6S)- 14917-83-0 with Safe Delivery
- Molecular Formula:C10H14O
- Molecular Weight:150.221
- Boiling Point:50 - 54 °C (0.03 mmHg)
- PSA：17.07000
- LogP:2.17770
14917-83-0 Relevant articles
-
Buechi,G. et al.
, p. 6473 - 6478 (1969)
-
Aromatic annulation of alicyclic α,β-unsaturated aldehydes: Synthesis of chirally substituted tetrahydronaphthalenes
Brenna, Elisabetta,Fuganti, Claudio,Serra, Stefano
, p. 365 - 366 (1998)
Chiral 2-tetrahydronaphthalene-carboxyli...
-
Buechi,G. et al.
, p. 4113 - 4114 (1966)
-
Stereoselective synthesis of carane-based chiral β- And γ-amino acid derivatives via conjugate addition
Szakonyi, Zsolt,Csor, árpád,Haukka, Matti,Fül?p, Ferenc
, p. 4846 - 4852 (2015)
Michael addition of dibenzylamine to (-)...
Stereoselective Synthesis and Modelling-Driven Optimisation of Carane-Based Aminodiols and 1,3-Oxazines as Catalysts for the Enantioselective Addition of Diethylzinc to Benzaldehyde
Szakonyi, Zsolt,Cs?r, árpád,Csámpai, Antal,Fül?p, Ferenc
, p. 7163 - 7173 (2016/05/19)
The reductive amination of (-)-2-carene-...
Seven-Ring Annulation: A Linch-Pin Approach to a Tetracyclic Precursor of the Lathrane Diterpenes
Braish, T. F.,Saddler, J. C.,Fuchs, P. L.
, p. 3647 - 3658 (2007/10/02)
The synthesis of a chiral tetracyclic in...
14917-83-0 Process route
-
-
78012-40-5
(4S)-4-(1-chloro-1-methylethyl)-1-cyclohexenecarboxaldehyde
-
![(1R,6S)-7,7-dimethylbicyclo[4.1.0]hept-2-ene-3-carboxaldehyde](/upload/2026/8/0ccc569285dd422faa461249311e0d04_d93be4fa-6a2d-440c-ac68-7741d1535122.png)
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14917-83-0,247911-68-8
(1R,6S)-7,7-dimethylbicyclo[4.1.0]hept-2-ene-3-carboxaldehyde
Conditions
| Conditions | Yield |
|---|---|
|
With
potassium tert-butylate;
In
tetrahydrofuran;
at 0 ℃;
|
94% |
|
With
potassium tert-butylate;
In
tetrahydrofuran;
at 0 ℃;
Yield given;
|
-
-
18031-40-8
(S)-(-)-perillaldehyde
-
-
14917-83-0,247911-68-8
(1R,6S)-7,7-dimethylbicyclo[4.1.0]hept-2-ene-3-carboxaldehyde
Conditions
| Conditions | Yield |
|---|---|
|
(S)-(-)-perillaldehyde;
With
hydrogen bromide; acetic acid;
at 0 - 25 ℃;
for 2.5h;
With
tert-Amyl alcohol; potassium tert-butylate;
at 0 - 25 ℃;
for 3h;
|
45% |
|
Multistep reaction;
(i) HBr, AcOH, (ii) KOtBu, t-amyl alcohol;
|
|
|
With
potassium tert-butylate; hydrogen bromide; acetic acid;
Multistep reaction;
|
|
|
Multi-step reaction with 2 steps
1: sulfur dioxide, hydrogen chloride (gas) / 0.67 h / -45 °C
2: potassium tert-butoxide / tetrahydrofuran / 0 °C
With
hydrogenchloride; sulfur dioxide; potassium tert-butylate;
In
tetrahydrofuran;
|
|
|
Multi-step reaction with 2 steps
1: HCl gas / liquid sulphur dioxide / 0.33 h / -45 °C
2: 94 percent / potassium tert-butoxide / tetrahydrofuran / 0 °C
With
hydrogenchloride; potassium tert-butylate;
In
tetrahydrofuran;
|
|
|
(S)-(-)-perillaldehyde;
With
hydrogen bromide;
With
potassium tert-butylate;
|
14917-83-0 Upstream products
-
18031-40-8
(S)-(-)-perillaldehyde
-
78012-40-5
(4S)-4-(1-chloro-1-methylethyl)-1-cyclohexenecarboxaldehyde
14917-83-0 Downstream products
-
115047-54-6
<(1'S,2'R,3'S,4'S)-1'-hydroxy-3'-(phenylsulfonyl)-4'-methylcyclopent-2'-yl><(1R,6S)-7,7-dimethylbicyclo<4.1.0>hept-2-en-3-yl>bis(methylthio)methane
-
115047-57-9
(2R,3S,4S)-3-Benzenesulfonyl-2-[((1R,6S)-7,7-dimethyl-bicyclo[4.1.0]hept-2-en-3-yl)-bis-methylsulfanyl-methyl]-4-methyl-cyclopentanone
-
115047-41-1
2-<(2R,3S,4S)-4-methyl-1-oxo-3-(phenylsulfonyl)-2-cyclopentyl>-2-<(1R,6S)-7,7-dimethylbicyclo<4.1.0>hept-2-en-3-yl>-1,3-dithiacyclohexane
-
115047-50-2
2-<(1'S,2'R,3'R,4'S')-1'-((tert-butyldimethylsilyl)oxy)-4'-methyl-3'-(phenylsulfonyl)cyclopent-2'-yl>-3-(bis(methylthio)methyl)-(1R,6S)-7,7-dimethylbicyclo<4.1.0>hept-3-ene