- CAS
- Purity
- 4403-71-8
- 99%
Location：Home > Pharmaceutical
Factory Sells Best Quality 4-Aminobenzylamine 4403-71-8 with GMP standards
- Molecular Formula: C7H10N2
- Molecular Weight: 122.17
- Appearance/Colour: White to light yellow crystalline powder
- Vapor Pressure: 4.84E-05mmHg at 25°C
- Melting Point: 37 °C
- Refractive Index: n20/D 1.61(lit.)
- Boiling Point: 349 °C at 760 mmHg
- PKA: 9.65±0.10(Predicted)
- Flash Point: 132 °C
- PSA： 52.04000
- Density: 1.093 g/cm3
- LogP: 2.00900
4-Aminobenzylamine(Cas 4403-71-8) Usage
|
General Description |
4-Aminobenzylamine is an aromatic amine. Diazonium cations of 4-aminobenzylamine were generated in situ with sodium nitrite in aqueous HCl, which were used for the modification of glassy carbon electrode by aryl groups having an aliphatic amine group. |
InChI:InChI=1/C7H10N2/c8-5-6-1-3-7(9)4-2-6/h1-4H,5,8-9H2
4403-71-8 Relevant articles
Catalysis of polymer-protected Ni/Pd bimetallic nano-clusters for hydrogenation of nitrobenzene derivatives
Lu, Ping,Toshima, Naoki
, p. 751 - 758 (2000)
Poly(N-vinyl-2-pyrrolidone)-protected Ni...
A State-of-the-Art Heterogeneous Catalyst for Efficient and General Nitrile Hydrogenation
Formenti, Dario,Mocci, Rita,Atia, Hanan,Dastgir, Sarim,Anwar, Muhammad,Bachmann, Stephan,Scalone, Michelangelo,Junge, Kathrin,Beller, Matthias
supporting information, p. 15589 - 15595 (2020/10/02)
Cobalt-doped hybrid materials consisting...
Cobalt pincer complexes for catalytic reduction of nitriles to primary amines
Schneek?nig, Jacob,Tannert, Bianca,Hornke, Helen,Beller, Matthias,Junge, Kathrin
, p. 1779 - 1783 (2019/04/27)
Various cobalt pincer type complexes 1-6...
Mild palladium-catalysed highly efficient hydrogenation of CN, C-NO2, and CO bonds using H2 of 1 atm in H2O
Liu, Yaxu,He, Shaopo,Quan, Ziyi,Cai, Huizhuo,Zhao, Yang,Wang, Bo
supporting information, p. 830 - 838 (2019/02/27)
Here we present the first example of a m...
A ppm level Rh-based composite as an ecofriendly catalyst for transfer hydrogenation of nitriles: Triple guarantee of selectivity for primary amines
Liu, Lei,Li, Jifan,Ai, Yongjian,Liu, Yuhong,Xiong, Jialiang,Wang, Hongdong,Qiao, Yijun,Liu, Wenrui,Tan, Shanchao,Feng, Shaofei,Wang, Kunpeng,Sun, Hongbin,Liang, Qionglin
, p. 1390 - 1395 (2019/03/26)
Hydrogenation of nitriles to afford amin...
4403-71-8 Process route
-
-
873-74-5
4-Aminobenzonitrile
-
-
4403-71-8
(4-aminomethyl)aniline
Conditions
| Conditions | Yield |
|---|---|
|
With
Zr12(μ3-O)5[(μ3-O)CoCl]8[(μ2-O)2(μ3-O)CoCl]3Li3(triphenyldicarboxylate)9; hydrogen;
In
toluene;
at 110 ℃;
for 42h;
under 30003 Torr;
Catalytic behavior;
Inert atmosphere;
Schlenk technique;
|
100%
|
|
With
[bis(2-methylallyl)cycloocta-1,5-diene]ruthenium(II); potassium tert-butylate; hydrogen bromide; hydrogen; 2-((di-iso-propylphosphino)methyl)-1-methyl-1H-imidazole;
In
tetrahydrofuran; water; acetone; toluene;
at 80 ℃;
for 5.5h;
under 37503.8 Torr;
Inert atmosphere;
Schlenk technique;
Autoclave;
|
99%
|
|
With
ammonia; hydrogen;
In
water; isopropyl alcohol;
at 80 ℃;
for 24h;
under 15001.5 Torr;
Autoclave;
|
99%
|
|
With
C25H19N3ORuS; potassium tert-butylate;
In
iso-butanol;
at 120 ℃;
for 0.5h;
Reagent/catalyst;
Inert atmosphere;
|
92%
|
|
With
[Ru(H)(BH4)(CO)(PPh3)(3-(di-tert-butylphosphino)-N-((1-methyl-1H-imidazol-2 yl)methyl)propylamine)]; hydrogen;
In
isopropyl alcohol;
at 70 ℃;
for 3h;
Inert atmosphere;
Autoclave;
|
88%
|
|
With
C19H34Cl2CoN2P; hydrogen; sodium ethanolate; sodium triethylborohydride;
In
benzene;
at 135 ℃;
for 36h;
under 22502.3 Torr;
Autoclave;
|
86%
|
|
With
sodium tetrahydroborate; cobalt(II) sulphate heptahydrate;
In
ethanol; water;
at 0 - 21 ℃;
for 0.05h;
|
78%
|
|
With
C28H29Cl2CoNP2; hydrogen; sodium triethylborohydride;
In
1,4-dioxane;
at 80 ℃;
for 6h;
under 37503.8 Torr;
|
76%
|
|
With
ammonia; hydrogen;
Raney-Urushibara-Ni;
In
methanol;
|
|
|
With
hydrogen;
poly(N-vinyl-2-pyrrolidone); nickel-palladium;
In
ethanol;
at 30 ℃;
for 30h;
under 760 Torr;
|
|
|
With
[bis(2-methylallyl)cycloocta-1,5-diene]ruthenium(II); 1,1'-bis(diphenylphosphino)ferrocene; potassium tert-butylate; hydrogen;
In
toluene;
at 140 ℃;
for 1h;
under 37503.8 Torr;
chemoselective reaction;
Inert atmosphere;
Autoclave;
|
69 %Chromat.
|
|
With
MnBr(CO)2[NH(CH2CH2P(iPr)2)2]; hydrogen; sodium t-butanolate;
In
toluene;
at 120 ℃;
for 24h;
under 37503.8 Torr;
Autoclave;
|
42 %Chromat.
|
|
With
[bis(2-methylallyl)cycloocta-1,5-diene]ruthenium(II); {[(phenylphosphinediyl)bis(2,1-phenylene)]bis(methylene)}bis(di-tert-butylphosphine); hydrogen;
In
isopropyl alcohol;
at 50 ℃;
for 17h;
under 11251.1 Torr;
Inert atmosphere;
Autoclave;
|
99 %Chromat.
|
|
4-Aminobenzonitrile;
With
cobalt(III) acetylacetonate; tris(2-(dicyclohexylphosphanyl)ethyl)phosphane;
In
tert-butyl alcohol;
Sealed tube;
Inert atmosphere;
With
potassium tert-butylate;
In
tert-butyl alcohol;
Sealed tube;
Inert atmosphere;
With
hydrogen;
In
tert-butyl alcohol;
at 120 ℃;
for 18h;
under 22502.3 Torr;
Autoclave;
|
97 %Chromat.
|
|
With
C43H38Cl2CoN5; potassium tert-butylate; hydrogen; sodium triethylborohydride;
In
toluene;
at -196.16 - 115 ℃;
for 8h;
under 760.051 - 3040.2 Torr;
|
|
|
With
fac-1,2-bis(dipropylphosphaneyl)ethane tricarbonyl manganese(I) bromide; potassium tert-butylate; hydrogen;
In
toluene;
at 100 ℃;
for 18h;
under 37503.8 Torr;
Autoclave;
|
85 %Chromat.
|
|
With
hydrogen;
In
water;
at 20 ℃;
for 3h;
under 760.051 Torr;
pH=1;
chemoselective reaction;
Catalytic behavior;
Green chemistry;
|
85 %Chromat.
|
|
With
formic acid; triethylamine;
at 40 ℃;
for 3h;
|
94 %Chromat.
|
|
With
hydrogenchloride; oxalic acid;
In
water;
at 20 ℃;
for 1h;
chemoselective reaction;
Kinetics;
UV-irradiation;
|
92 %Chromat.
|
|
With
fac-[Mn(1,2-bis(di-n-propylphosphino)ethane)(CO)3(CH3)]; hydrogen;
In
toluene;
at 100 ℃;
for 18h;
under 37503.8 Torr;
Autoclave;
|
71 %Chromat.
|
-
-
849042-08-6
benzyl N-(4-cyanophenyl)carbamate
-
-
4403-71-8
(4-aminomethyl)aniline
Conditions
| Conditions | Yield |
|---|---|
|
With
methanol; sodium tetrahydroborate; nickel(II) chloride hexahydrate;
at 20 ℃;
for 0.25h;
chemoselective reaction;
|
72%
|
4403-71-8 Upstream products
-
7409-30-5
p-nitrobenzylamine
-
100880-61-3
2-(4-amino-benzyl)-isoindole-1,3-dione
-
56222-10-7
N-(4-nitrobenzyl)acetamide
-
102677-62-3
chloro-acetic acid-(4-acetylamino-benzylamide)
4403-71-8 Downstream products
-
99741-73-8
1-isocyanate-4-(isocyanatomethyl)benzene
-
96783-64-1
(4-amino-benzyl)-guanidine; sulfate
-
774227-01-9
(4-amino-benzyl)-guanidine; dihydrochloride
-
696-60-6
4-aminomethylphenol