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N,N'-DIETHYL-N,N'-DIPHENYLUREA


  • CAS
  • Purity
  • 85-98-3
  • 99%
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Chinese Factory Supply Wholesale N,N'-DIETHYL-N,N'-DIPHENYLUREA 85-98-3 with Cheap Price

  • Molecular Formula: C17H20N2O
  • Molecular Weight: 268.359
  • Appearance/Colour: white crystalline powder 
  • Vapor Pressure: 7.74E-06mmHg at 25°C 
  • Melting Point: 73-75 °C(lit.) 
  • Refractive Index: 1.591 
  • Boiling Point: 379 °C at 760 mmHg 
  • PKA: 0.63±0.50(Predicted) 
  • Flash Point: 150.8 °C 
  • PSA: 23.55000 
  • Density: 1.118 g/cm3 
  • LogP: 4.15940 

N,N'-DIETHYL-N,N'-DIPHENYLUREA(Cas 85-98-3) Usage

General Description

White flakes or white crystalline solid. Peppery odor.

Air & Water Reactions

Insoluble in water.

Reactivity Profile

N,N'-DIETHYL-N,N'-DIPHENYLUREA is an amide. Amides/imides react with azo and diazo compounds to generate toxic gases. Flammable gases are formed by the reaction of organic amides/imides with strong reducing agents. Amides are very weak bases (weaker than water). Imides are less basic yet and in fact react with strong bases to form salts. That is, they can react as acids. Mixing amides with dehydrating agents such as P2O5 or SOCl2 generates the corresponding nitrile. The combustion of these compounds generates mixed oxides of nitrogen (NOx). N,N'-DIETHYL-N,N'-DIPHENYLUREA is incompatible with acids and oxidizing agents. N,N'-DIETHYL-N,N'-DIPHENYLUREA reacts violently when severely shocked or exposed to extreme temperatures.

Health Hazard

ACUTE/CHRONIC HAZARDS: N,N'-DIETHYL-N,N'-DIPHENYLUREA may react violently when severely shocked or heated to extreme temperatures.

Fire Hazard

N,N'-DIETHYL-N,N'-DIPHENYLUREA is combustible.

Flammability and Explosibility

Nonflammable

Safety Profile

Poison by intraperitoneal route. Moderately toxic by ingestion. Combustible when exposed to heat or flame. Probably a slight explosion hazard, although it is a component of smokeless explosive mixtures. When heated o decomposition it burns and emits very toxic fumes of NOx. To fight fire, use dry chemical, CO2, spray or mist. An explosion regulator.

InChI:InChI=1/C17H20N2O/c1-3-18(4-2)17(20)19(15-11-7-5-8-12-15)16-13-9-6-10-14-16/h5-14H,3-4H2,1-2H3

85-98-3 Relevant articles

Palladium-catalyzed decarbonylative C–N coupling to convert arylcarbamoyl chlorides to urea derivatives

Fan, Aihong,Peng, Jinsong,Zhou, Dun,Li, Xiang,Chen, Chunxia

supporting information, p. 1 - 12 (2020/07/27)

This paper describes the development of ...

Organic ligand and solvent free oxidative carbonylation of amine over Pd/TiO2 with unprecedented activity

Liu, Shujuan,Dai, Xingchao,Wang, Hongli,Shi, Feng

supporting information, p. 4040 - 4045 (2019/08/07)

A highly active Pd/TiO2 catalyst system ...

PHASE-TRANSFER CATALYZED N-ALKYLATION OF sym-N,N'-DIARYLUREAS

Kalkote, U. R.,Choudhary, A. R.,Ayyangar, N. R.

, p. 83 - 87 (2007/10/03)

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85-98-3 Process route

N-ethyl-N-phenyl carbamoyl chloride
33758-39-3

N-ethyl-N-phenyl carbamoyl chloride

ethyl centralite
85-98-3

ethyl centralite

Conditions
Conditions Yield
With tetrakis(triphenylphosphine) palladium(0); potassium hydrogencarbonate; In 1,4-dioxane; at 100 ℃; for 48h; Schlenk technique; Inert atmosphere;
59%
diethyl sulfate
64-67-5

diethyl sulfate

bis(diphenyl)urea
102-07-8

bis(diphenyl)urea

ethyl centralite
85-98-3

ethyl centralite

Conditions
Conditions Yield
With sodium hydroxide; potassium carbonate; tetra(n-butyl)ammonium hydrogensulfate; In toluene; for 3h; Heating;
97%

85-98-3 Upstream products

  • 110-86-1
    110-86-1

    pyridine

  • 33758-39-3
    33758-39-3

    N-ethyl-N-phenyl carbamoyl chloride

  • 55-21-0
    55-21-0

    benzamide

  • 4338-94-7
    4338-94-7

    N ,N '-diethyl-N ,N '-diphenyl-thiourea

85-98-3 Downstream products

  • 3846-49-9
    3846-49-9

    1,3-diethyl-1,3-bis(4-nitrophenyl)urea

  • 4596-98-9
    4596-98-9

    1,3-bis(2,4-dinitrophenyl)-1,3-diethylurea

  • 1421853-53-3
    1421853-53-3

    MoCl4 ((EtPhN)2 CO)

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